Tecnologia em Metalurgia, Materiais e Mineração
https://tecnologiammm.com.br/article/doi/10.4322/2176-1523.0988
Tecnologia em Metalurgia, Materiais e Mineração
Artigo Original

SHATTUCKITE SYNTHESIS AND THE PATTERN FORMATION BY THE SCANNING LASER BEAM

Sergey, Maximovskii; Alexander, Turyanskiy; Konstantin, Bogonosov; Sergey, Gizha; Viacheslav, Senkov; Igor, Pirshin

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Abstract

Using X-ray diffraction it has been demonstrated that polycrystalline shattuckite can be synthesized by pulsed IR laser excitation of the thin layer of CuCl2 aqueous solution with an organosilicon compound placed upon a paper or polymeric film substrate. This process can be realized directly in standard atmospheric conditions at room temperature. Samples exhibit change of colour at different angles of illumination due to birefringence and interference. Any desired pattern can be obtained by scanning of a laser beam on the substrate surface.

Keywords

Synthesis, Shattuckite, Diffraction.

Referências

1 Bowell R, Cook R. Connoisseur’s Choice: Shattuckite, Kunene District, Kaokoveld, Namibia. Rocks and Minerals. 2009;84(6):544-550. http://dx.doi.org/10.1080/00357520903272231.

2 Evans HT, Mrose ME. The crystal chemistry of the hydrous copper silicates, shattuckite and planchéite. The American Mineralogist. 1977;62(5-6):491-502.

3 Anthony JW, Bideaux RA, Bladh KW, Nichols MC, editors. Handbook of mineralogy. Arizona: Mineral Data Publishing; 2003. (vol. 2).

4 Sarma KBN, Reddy BJ, Lakshman SVJ. Absorption spectra of Cu2+ in shattuckite and plancheite. Physics Letters. [Part A]. 1982;92(6):305-308. http://dx.doi.org/10.1016/0375-9601(82)90093-7.

5 Frost RL, Xi Y. Raman spectroscopic study of the mineral shattuckite Cu5 (SiO3 ) 4 (OH)2 . Spectrochimica Acta. Part A: Molecular and Biomolecular Spectroscopy. 2012;87:241-244. http://dx.doi.org/10.1016/j.saa.2011.11.046. PMid:22177220.

6 Koshelev AV, Zvereva EA, Chareev DA, Volkova OS, Vymazalova A, Laufek F, et al. The long-range magnetic order and underlying spin model in shattuckite Cu5(SiO3)4(OH). Physics and Chemistry of Minerals. 2016;43(1):43-49. http://dx.doi.org/10.1007/s00269-015-0772-7.

7 Kawamura K, Kawahara A. The crystal structure of synthetic copper sodium silicate: Cu3 Na2 (Si4 O12). Acta Crystallographica. 1976;B32(8):2419-2422. http://dx.doi.org/10.1107/S0567740876007887.

8 Tur’yanskiĭ AG, Aprelov SA, Gerasimenko NN, Pirshin IV, Senkov VM. Relative X-ray reflectometry of discrete layered structures. Technical Physics Letters. 2007;33(3):224-227. http://dx.doi.org/10.1134/S1063785007030121.

9 Kudryashov SI, Lyon K, Allen SD. Near-field thermal radiative transfer and thermoacoustic effects from vapor plumes produced by pulsed CO2 laser ablation of bulk water. Journal of Applied Physics. 2006;100(12):124908. http://dx.doi.org/10.1063/1.2402388.

10 Vodop’yanov LK, Kozlov PS, Kucherenko IV, Maksimovskii SN, Radutskii GA. Studying the possibility of applying the light-hydraulic effect to digital printing. Instruments and Experimental Techniques. 2003;46(4):549-553. http://dx.doi.org/10.1023/A:1025102703697.
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