Tecnologia em Metalurgia, Materiais e Mineração
Tecnologia em Metalurgia, Materiais e Mineração
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Hydrogen interaction in ultrafine grain duplex stainless steel 2205 aged after cold rolling

Loyslene Rabelo Fernandes, Thaís Braga de Abreu, Lisa Claeys, Tom Depover, Kim Verbeken, Dagoberto Brandão Santos

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Duplex stainless steels (DSS) have a microstructure of ferrite and austenite. These alloys have a high strength combined with ductility and good corrosion resistance. They are widely used in the petrochemical, paper and nuclear industries. However, like other stainless steels, they are susceptible to hydrogen embrittlement (HE). DSS 2205 samples were received under the condition of homogenization annealing (1050°C for 300 s and cooling in water). Then, they were cold rolled to 60% thickness reduction and annealed at 1100°C for 7200 s and aged at 850°C for 86400 s, then charged with hydrogen. Melt extraction analyzes were applied to quantify the hydrogen in the steel. In situ tensile tests, with simultaneous hydrogen charging, were used to assess the embrittlement caused by this element. Completing the hydrogen analyzes, thermal desorption spectra (TDS) were constructed. In the aged condition, the phases ferrite, austenite, sigma (σ), chi (χ) and carbide (M23C6 ) were identified. The DSS showed a considerable reduction in ductility, reaching 5% total elongation in the aged state. Hydrogen charging did not change this condition. Melt extraction revealed a hydrogen content in the microstructure of up to 50 wppm for the annealed condition, while for the aged sample it was 10 wppm.


Duplex stainless steel; Hydrogen embrittlement; Hydrogen absorption; Hydrogen diffusivity; Brittle fracture


1 Gunn R. Duplex stainless steels: microstructure, properties and applications. 1st ed. Cambridge: Abington Publishing; 1997.

2 Fargas G, Akdut N, Anglada M, Mateo A. Microstructural evolution during Industrial Rolling of a Duplex. ISIJ International. 2008;48:1596-1602.

3 Lo KH, Shek CH, Lai JKL. Recent developments in stainless steels. Materials Science Engineering E. 2009;65:39- 104.

4 Alvarez-Armas I. Duplex stainless steels: brief history and some recent alloys. Recent Patents on Mechanical Engineering. 2008;1:51-57.

5 Djaziri S, Li Y, Nematollahi GA, Grabowski B, Goto S, Kirchlechner C, et al. A new paradigm for exceptional steels. Advanced Materials. 2016;28:7753-7757.

6 Rosso M, Peter I, Suani D. About heat treatment and properties of duplex stainless steels. Journal Achievements Materials Manufacturing Engineering. 2013;59:26-36.

7 Hsieh C-C, Wu W. Overview of intermetallic sigma phase precipitation in stainless steels. ISRN Metallurgy. 2012;66:1-16.

8 Llorca-Isern N, López-Luque H, López-Jiménez I, Biezma MV. Identification of sigma and chi phases in duplex stainless steels. Materials Characterization. 2016;112:20-29.

9 Calliari I, Zanesco M, Ramous E. Influence of isothermal aging on secondary phases precipitation and toughness of duplex stainless steel SAF 2205. Journal of Materials Science. 2006;41:7643-7649.

10 Hosseini VA, Karlsson L, Wiesmann S, Fuertes N. Effect pf sigma phase morphology on the degradation of properties in a super duplex stainless steel. Materials (Basel). 2018;11:1-20. [MDPI]

11 Zheng W, Hardie D. The Effect of Hydrogen on the Fracture of a Commercial Duplex Stainless Steel. Corrosion Science. 1991;32:23-36.

12 Silverstein R, Sobol O, Boellinghaus T, Unger W, Eliezer D. Hydrogen behavior in SAF 2205 duplex stainless steel. Journal of Alloys and Compounds. 2017;695:2689-2695.

13 Silva BRS, Salvio F, Santos DS. Hydrogen induced stress cracking in UNS S32750 super duplex stainless steel tube weld joint. International Journal of Hydrogen Energy. 2015;40:17091-17101.

14 Robertson IM, Sofronis P, Nagao A, Martin ML, Wang S, Gross D, et al. Hydrogen Embrittlement Understood. Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science. 2015;46:2323-2341.

15 Maria GGB, Claeys L, Depover T, Santos DB, Verbeken K. The Hydrogen Induced Mechanical Degradation of Duplex Stainless Steel. Steel Research International. 2019;90:1-6.

16 Luo H, Dong CF, Liu ZY, Maha MT, Li G. Characterization of hydrogen charging of 2205 duplex stainless steel and its correlation with hydrogen-induced cracking. Materials and Corrosion. 2013;64:26-33.

17 Iacoviello F, Habashi M, Avallini M. Hydrogen embrittlement in the duplex stainless steel Z2CND2205 hydrogencharged at 200°C. Materials Science and Engineering A. 1997;224:116-124.

18 Kuroda T. Role of sigma phase on hydrogen embrittlement of super duplex stainless steels. Transactions of JWRI. 2005;34(2):63-68.

19 Vaňová P, Sojka J. Hydrogen embrittlement of duplex steel tested using slow strain rate test. Metalurgija. 2014;53(2):163-166.

20 Escobar DP, Verbeken K, Duprez L, Verhaghe M. Evaluation of hydrogen trapping in high strength steels by thermal desorption spectroscopy. Materials Science and Engineering A. 2012;551:50-58.

21 Claeys L, Cnockaert V, Depover T, De Graeve I, Verbeken K. Critical assessment of the evaluation of thermal desorption spectroscopy data for duplex stainless steels: A combined experimental and numerical approach. Acta Materialia. 2020;186:190-198.

22 Dabah E, Lisitsyn V, Eliezer D. Performance of hydrogen trapping and phase transformation in hydrogenated duplex stainless steels. Materials Science and Engineering A. 2010;527:4851-4857.

23 Luu WC, Liu PW, Wu JK. Hydrogen transport and degradation of a commercial duplex stainless steel. Corrosion Science. 2002;44(8):1783-1791.

24 Matsuo T, Yamabe J, Matsuoka S. Effects of hydrogen on tensile properties and fracture surface morphologies of Type 316L stainless steel. International Journal of Hydrogen Energy. 2014;39:3542-3551.

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