Tecnologia em Metalurgia, Materiais e Mineração
https://tecnologiammm.com.br/article/doi/10.4322/2176-1523.20212483
Tecnologia em Metalurgia, Materiais e Mineração
Artigo Original

Hidrothermal liquefaction of lignocellulosic residue to produce sustainable materials: fractions characterization

Solange Kazue Utimura, Denise Crocce Romano Espinosa, Marco Antonio das Neves, Isao Kobayashi, Mitsutoshi Nakajima, Cristina Stewart Bogsan

Downloads: 0
Views: 976

Resumo

In this study, hydrothermal liquefaction (HTL) of sugarcane bagasse (SCB) acquired in Okinawa (Japan) was performed at 170, 200 and 230 °C, pressures from 1 to 3 MPa and retention time of 30 min. These experiments were executed in a 500 mL reactor with 5 g SCB and 95 mL deionized water in inert nitrogen condition. The highest sugar yields were obtained at the concentration of 20.25 g/L at 230 °C, 3 MPa and 30 min. In accordance with elemental analysis, highest carbon content values were 55.31% at 200 °C and 59.9% at 230 °C. The chemical composition was analyzed through SEM and FTIR. HTL has been applied to obtain biomaterials from agricultural wastes which can be incorporated or converted into new value-added products. HTL in subcritical conditions is an interesting hydrolysis process and has advantages of reduced energy consumption and water reaction environment.

Palavras-chave

Hydrothermal liquefaction; Sugarcane bagasse; Subcritical conditions; Lignocellulosic residues; Materials; Waste

Referências

1 Kumar G, Dharmaraja J, Arvindnarayan S, Shoban SP, Bakonyi P, Saratale GD, et al. A comprehensive review on thermochemical, biological, biochemical and hybrid conversion methods of bio-derived lignocellulosic molecules into renewable fuels. Fuel. 2019;251:352-367.

2 Cho EJ, Trinh LTP, Song Y, Lee YG, Bae HJ. Bioconversion of biomass waste into high value chemicals. Bioresource Technology. 2020;298:122386.

3 Mayanga-Torres PC, Lachos-Perez D, Rezende CA, Prado JM, Ma Z, Tompsett GT, et al. Valorization of coffee industry residues by subcritical water hydrolysis: recovery of sugars and phenolic compounds. The Journal of Supercritical Fluids. 2017;120:75-85.

4 Baloch HA, Nizamuddin S, Siddiqui MTH, Mubarak NM, Dumbre DK, Srinivasan MP, et al. Sub-supercritical liquefaction of sugarcane bagasse for production of bio-oil and char: effect of two solvents. Journal of Environmental Chemical Engineering. 2018;6(5):6589-6601.

5 Jiang W, Kumar A, Adamopoulos S. Liquefaction of lignocellulosic materials and its applications in wood adhesives – A review. Industrial Crops and Products. 2018;124:325-342.

6 Kumar M, Oyedun AO, Kumar A. A review on the current status of various hydrothermal technologies on biomass feedstock. Renewable & Sustainable Energy Reviews. 2018;81:1742-1770.

7 Isikgor FH, Remzi Becer C. Lignocellulosic biomass: a sustainable platform for production of bio-based chemicals and polymers. Polymer Chemistry. 2015;6(25):4497-4559.

8 Rao Y, Xiang B. Determination of total ash and acid-insoluble ash of chinese herbal medicine Prunellae Spica by infrared spectroscopy. Yakugaku Zasshi. 2009;129(7):881-886.

9 Abdelmoez W, Nage SM, Bastawess A, Ihab A, Yoshida H. Subcritical water technology for wheat straw hydrolysis to produce value added products. Journal of Cleaner Production. 2014;70:68-77.

10 Zhu G, Zhu X, Fan Q, Wan X. Production of reducing sugars from bean dregs waste by hydrolysis in subcritical water. Journal of Analytical and Applied Pyrolysis. 2011;90(2):182-186.

11 Prado JM, Follegatti-Romero LA, Forster-Carneiro T, Rostagno MA, Maugeri F Fo, Meireles MAA. Hydrolysis of sugarcane bagasse in subcritical water. The Journal of Supercritical Fluids. 2014;86:15-22.

12 Toor SS, Rosendahl L, Rudolf A. Hydrothermal liquefaction of biomass: a review of subcritical water technologies. Energy. 2011;36(5):2328-2342.

13 Lachos-Perez D, Martinez-Jimenez F, Rezende CA, Tompsett G, Timko M, Forster-Carneiro T. Subcritical water hydrolysis of sugarcane bagasse: an approach on solid residues characterization. The Journal of Supercritical Fluids. 2016;108:69-78.

14 Russo C, Stanzione F, Tregrossi A, Ciajolo A. Infrared spectroscopy of some carbon-based materials relevant in combustion: qualitative and quantitative analysis of hydrogen. Carbon. 2014;74:127-138.

15 Peng TY, Wu SB. The structural and thermal characteristics of wheat straw hemicelluloses. Journal of Analytical and Applied Pyrolysis. 2010;88(2):134-139.

16 Bian J, Peng F, Peng XP, Xu F, Sun RC, Kennedy JF. Isolation of hemicelluloses from sugarcane bagasse at different temperatures: structure and properties. Carbohydrate Polymers. 2012;88(2):638-645.


Submetido em:
23/09/2020

Aceito em:
08/01/2021

60ba1a6aa95395478c3490e4 tmm Articles
Links & Downloads

Tecnol. Metal. Mater. Min.

Share this page
Page Sections