Tecnologia em Metalurgia, Materiais e Mineração
https://tecnologiammm.com.br/article/doi/10.4322/2176-1523.20222726
Tecnologia em Metalurgia, Materiais e Mineração
Artigo Original – Special Issue 75th ABM Annual Congress - PART I

Measurements of hardness, young’s modulus, and fracture toughness of solar grade silicon obtained from metallurgical grade silicon

Denir Paganini Nascimento, Marcelo Aquino Martorano, Caio Cesar Cebalos de Almeida, Angelo Fernando Padilha

Downloads: 0
Views: 418

Abstract

Young modulus and toughness (KIC) of bulk solar grade silicon (SoG-Si) obtained by directional solidification of metallurgical grade silicon were determined. The Young modulus was measured by the technique of impulse excitation of vibration and KIC was determined using the indentation method. Measurement values agree well with those available in the literature. The indentation method proved to be a reliable, relatively simple, inexpensive, and fast experimental method to measure KIC in SoG-Si.

Keywords

Solar grade silicon; Young’s modulus; Toughness; Indentation method.

Referências

1 Lima ML, Martorano MA, Ferreira JB No. Macrosegregation of impurities in a metallurgical silicon ingot after transient directional solidification. Materials Research. 2017 [cited 2022 June 16];20(4):1129-1135. Available at: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000401129&lng=en&tlng=en

2 Lei Y, Ma X, Wang Y, Chen Z, Ren Y, Ma W, et al. Recent progress in upgrading metallurgical-grade silicon to solar-grade silicon via pyrometallurgical routes. International Journal of Minerals, Metallurgy and Materials. 2022 [cited 2022 June 16];29(4):767-782. Available at: https://link.springer.com/article/10.1007/s12613-022-2418-3

3. Martorano MA, Ferreira Neto JB, Oliveira TS, Tsubaki TO. Refining of metallurgical silicon by directional solidification. Materials Science and Engineering: B. 2011;176(3):217-226. http://dx.doi.org/10.1016/j.mseb.2010.11.010

4 Chigondo F. From metallurgical-grade to solar-grade silicon: an overview. Silicon. 2018 [cited 2022 June 16];10(3):789-798. Available at: https://link.springer.com/article/10.1007/s12633-016-9532-7

5 Marques FC, Cortes ADS, Mei PR. Solar cells fabricated in upgraded metallurgical silicon, obtained through vacuum degassing and czochralski growth. Silicon. 2019 [cited 2022 June 16];11(1):77-83. Available at: http://link.springer.com/10.1007/s12633-018-9860-x

6 Louwen A, van Sark W, Schropp R, Faaij A. A cost roadmap for silicon heterojunction solar cells. Solar Energy Materials and Solar Cells. 2016 [cited 2022 June 16];147:295-314. Available at: https://linkinghub.elsevier.com/retrieve/pii/S0927024815006741

7 Wu M, Murphy JD, Jiang J, Wilshaw PR, Wilkinson AJ. Microstructural evolution of mechanically deformed polycrystalline silicon for kerfless photovoltaics. Physica Status Solidi. 2019 [cited 2022 June 16];216(10):1800578. Available at: https://onlinelibrary.wiley.com/doi/full/10.1002/pssa.201800578

8 Brodie R, Bahr D. Fracture of polycrystalline silicon. Materials Science and Engineering: A. 2003 [cited 2022 June 16];351(1–2):166-173. Available at: https://linkinghub.elsevier.com/retrieve/pii/S0921509302008298

9 Anstis GR, Chantikul P, Lawn BR, Marshall DB. A critical evaluation of indentation techniques for measuring fracture toughness: I, direct crack measurements. Journal of the American Ceramic Society. 1981 [cited 2022 June 16];64(9):533-538. Available at: https://onlinelibrary.wiley.com/doi/full/10.1111/j.1151-2916.1981.tb10320.x

10 Şakar-Deliormanli A, Güden M. Microhardness and fracture toughness of dental materials by indentation method. Journal of Biomedical Materials Research. Part B, Applied Biomaterials. 2006 [cited 2022 June 16];76B(2):257-264. Available at: https://onlinelibrary.wiley.com/doi/full/10.1002/jbm.b.30371

11 ASTM International [Internet]. Standard test method for dynamic young’s modulus, shear modulus, and poisson’s ratio by impulse excitation of vibration [cited 2022 June 16]. Available at: https://www.astm.org/e1876-21.html?msc lkid=bd3bea7bd14411ecb7f2db394c27f698

12 ASTM International [Internet]. Standard test methods for vickers hardness and knoop hardness of metallic materials [cited 2022 June 16]. Available at: https://www.astm.org/standards/e92?msclkid=14608947d14511ecb54e967ca 80fc100

13 Bowen P, Bonjour C, Carry C, Gonseth D, Hofmann H, Mari D, et al. Novel alumina titanium-carbonitride nickel composites. JOM. 1995 [cited 2022 June 16];47(11):56-58. Available at: http://link.springer.com/10.1007/BF03221312

14 Vogelaar GC. Analysis of intermetallic phases in silicon ingots of different thichness. In: Oye HA, Rong HM, Ceccaroli B, Nygaard L, Tuset JK, editors. Silicon for the chemical and solar industry III. Sandefjord: The Norwegian University of Science and Technology (NTNU); 1996. p. 95-112.

15 Schilz J, Langenbach M. Powder metallurgy of Ge, Si, and Ge-Si. Journal of Crystal Growth. 1993 [cited 2022 June 16];128(1–4):1197-1202. Available at: https://linkinghub.elsevier.com/retrieve/pii/S0022024807801230

16 Hopcroft MA, Nix WD, Kenny TW. What is the young’s modulus of silicon? Journal of Microelectromechanical Systems. 2010 [cited 2022 June 16];19(2):229-238. Available at: http://ieeexplore.ieee.org/document/5430873/17 Paggi M, Corrado M, Reinoso J. Fracture of solar-grade anisotropic polycrystalline Silicon: a combined phase field–cohesive zone model approach. Computer Methods in Applied Mechanics and Engineering. 2018 [cited 2022 June 16];330:123-148. Available at: https://www.sciencedirect.com/science/article/pii/S0045782517306928


Submetido em:
16/06/2022

Aceito em:
17/11/2022

6387a09aa9539530492b69c3 tmm Articles
Links & Downloads

Tecnol. Metal. Mater. Min.

Share this page
Page Sections