Tecnologia em Metalurgia, Materiais e Mineração
https://tecnologiammm.com.br/article/doi/10.4322/2176-1523.20242800
Tecnologia em Metalurgia, Materiais e Mineração
Artigo Original

Influence of pellets quaternary basicity on softening and melting properties

Jean Philippe Santos Gherardi de Alencar

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Abstract

The softening and melting zone is deemed the most critical region within a blast furnace. It is in this region that iron ore commences its softening and melting process, thereby obstructing the flow of ascending gases. The formation of a liquid phase within the ore or agglomerate, a phenomenon referred to as exudation, is intricately complex and strongly tied to the chemical composition of the burden material. Despite the challenges in replicating the conditions of the softening and melting zone at a laboratory scale, numerous studies have endeavored to establish a correlation between these chemical characteristics of the burden and its metallurgical properties. Through an extensive series of pellet tests, an investigation was conducted to determine such correlations taking into consideration the VALE’s Ferrous Technology Center database. The findings revealed that quaternary basicity serves as the most accurate predictor variable for describing the softening and melting properties of the pellets. This study supports the existing literature, suggesting that burdens with higher basicity exhibit a higher softening temperature and, consequently, a greater degree of indirect reduction. Conversely, more acidic pellets demonstrated a lower softening temperature, coupled with an extended softening interval. In conclusion, it was discovered that burdens with higher basicity also yielded lower maximum pressure values and pressure drop areas.

Keywords

 Iron ore; Softening; Melting; Blast furnace

Referências

1 Mourão MB, coord. Introdução à siderurgia. São Paulo: ABM; 2007.

2 Vieira DH. CPGEM–curso de pós-graduação em engenharia metalúrgica e de minas [tese]. Belo Horizonte: Universidade Federal de Minas Gerais; 2012.

3 De Castro AA. Avaliação de propriedades em altas temperaturas de pelotas para alto-forno [tese]. Ouro Preto: Universidade Federal de Ouro Preto; 2006.

4 Ritz VJ, Kortmann H. Reduction, softening and melting properties of pellets, sinters, lumpy ore and mixed blast furnace burden. In: Proceedings 2nd International Congress on the Science and Technology of Ironmaking and 57 th Ironmaking Conference; 1998; Toronyo. Toronto: Iron & Steel Society; 1998. p. 1635-1654.

5 Parreira AG. Estudo das propriedades a altas temperaturas de cargas metálicas constituídas por sínter de minério de ferro [dissertação]. Belo Horizonte: Universidade Federal de Minas Gerais; 2015.

6 Bakker T, Heerema RH. Determination of the fundamental mechanisms underlying softening and melting of blast furnace burden materials. In: Proceedings of the 2nd International Congress on the Science and Technology of Ironmaking and 57 th Ironmaking Conference; Toronto. Toronto: Iron & Steel Society; 1998. p. 1597-1608.

7 Barnaba P. Influence of chemical characteristics of softening and melting down properties of iron ore sinter. Ironmaking & Steelmaking. 1985;12(2):53-63.

8 Bueno PG. Metallurgical characteristics of Samarco Mineração product portfolio and their influences on Western European blast furnace operations [dissertação]. Belo Horizonte: Universidade Federal de Minas Gerais; 2015.

9 Nogueira PF. Blast furnace burden softening and melting phenomena [tese]. Pittsburgh: Carnegie Mellon University.

10 Silva FR, Lemos LR, Nogueira PF, Bressan M. Effect of ternary basicity of iron ore-fluxed pellets on melting and softening properties in a blast furnace. Metallurgical and Materials Transactions. B, Process Metallurgy and Materials Processing Science. 2021;52(1):69-76.

11 Khaki JV, Kashiwaya Y, Ishii K. High temperature behaviour of selffluxed pellets during heating up reduction. Ironmaking & Steelmaking. 1994;21(1):56-63.

12 Clixby G. Influence of softening and melting Properties of Burden materials on blast furnace operation. Ironmaking & Steelmaking. 1986;13(4):169-175.

13 Iljana M, Heikkinen EP, Fabritius T. Estimation of iron ore pellet softening in a blast furnace with computational thermodynamics. Metals. 2021;11(10):1515. http://doi.org/10.3390/met11101515.

14 Nogueira PF, Fruehan RJ. Blast furnace burden softening and melting phenomena: Part I. Pellet bulk interaction observation. Metallurgical and Materials Transactions. B, Process Metallurgy and Materials Processing Science. 2004;35:829-838. http://doi.org/10.1007/s11663-004-0077-6.

15 Qi Z, Shengli W, Mingyin K, Xinliang L, Laixin W, Yujue W. Studying on softening and melting behavior of lump ore in blast furnace. In: Hwang JY, Jiang T, Pistorius PC, Alvear F GRF, Yücel O, Cai L, Zhao B, et al., eds. Proceedings of the 7th International Symposium on High-Temperature Metallurgical Processing. Cham: Springer; 2016. cap. 88. https://doi.org/10.1007/978-3-319-48093-0_88.

16 Wang GL, Kang J, Zhang JL, Wang YZ, Wang ZY, Liu ZJ, et al. Softening–melting behavior of mixed burden based on low-magnesium sinter and fluxed pellets. International Journal of Minerals Metallurgy and Materials. 2020;28(4):621-628. http://doi.org/10.1007/s12613-020-2047-7.

17 Minitab. Interpretar os principais resultados para gráfico de linha ajustada. 2019. [cited 2022 Sep 22]. Available at: https://support.minitab.com/pt-br/minitab/20/help-and-how-to/statistical-modeling/regression/how-to/fitted-lineplot/interpret-the-results/key-results/

18 Hawkins DM. Identification of outliers. London: Chapman and Hall; 1980.

19 Dhirendra Ghosh and Andrew Vogt. Outliers: an evaluation of methodologies. In: Joint statistical meetings. Arlington: JSM Online Program; 2012. p. 3455-3460.


Submetido em:
22/09/2022

Aceito em:
12/08/2024

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