Study of the wear of MgO-C refractory in the slag line of steel ladles
Edgard Marcos Ribeiro, Marcos Vinicius Ribeiro da Cunha, Natália de Castro Bicalho, Rafael Ferreira Delfim Bueno, Helton Jackson Costa, Alamar Kasan Duarte, Vinicius dos Santos Ribeiro, Débora Guimarães da Silva, Wander Luiz Vasconcelos
Abstract
The refractory wear in the slag line of steel ladles is a key factor in steelmaking operations. Understanding the characteristics of the refractory materials used in this region and their interactions with the process is essential for safe operation and optimized performance. In this context, the objective of this study was to evaluate the microstructure of different refractory materials applied to the slag line of steel ladles, identifying the types of magnesia used in each material, the presence of antioxidants, physical properties, and the interaction of each with two typical types of secondary refining slags. Six different commercial brands of MgO-C refractory materials were analyzed through laboratory tests, including chemical analysis, bulk density and apparent porosity and cold crushing strength (CCS), both in the as-received condition and after exposure to 1400 °C for 1 hour in a reducing atmosphere, oxidation resistance, and static corrosion tests. Refractory materials composed exclusively of fused magnesia grains, with larger crystal sizes and a well-distributed graphite matrix, demonstrated greater resistance to chemical attack by slags.
Keywords
References
1 Araújo LA. Manual de siderurgia. 2. ed. São Paulo: Arte e Ciência; 2005.
2 Duarte A. Classificação de Refratários. In: Curso fundamentos de refratários. Belo Horizonte: [s.n.]; 2012.
3 Costa HJ, Ribeiro EM. Curso academia de siderurgia da ArcelorMittal Monlevade. João Monlevade (MG); 2016.
4 Leite FC, Luz AP, Pandolfelli VC. Características e mecanismos de desgaste dos refratários MgO-C usados na linha de escória de panelas de aço. São Carlos (SP): Universidade Federal de São Carlos; 2014.
5 Jansen HW, Daldrup HG. Refractories in steel ladles: materials and design. In: AISTech Conference Proceedings; 2004; Warrendale (PA). Warrendale (PA): Association for Iron & Steel Technology; 2004. Vol. 1.
6 Freire MV, Trujillo JJ, Silva SLC, Costa e Silva ALV. Um enfoque termodinâmico para o estudo do comportamento de refratários MgO-C na linha de escória de panelas para aço líquido. In: Associação Brasileira de Metalurgia, Materiais e Mineração. Anais do 47º Seminário de Aciaria – Internacional, ABM Week; 2016; Rio de Janeiro. São Paulo: ABM; 2016.
7 Kundu R, Sarkar R. MgO-C refractories: a detailed review of these irreplaceable refractories in steelmaking. InterCeram: International Ceramic Review. 2021;70:46-55.
8 Li J, Zhang Y, Shao S, Zhang S. Comparative life cycle assessment of conventional and new fused magnesia production. Journal of Cleaner Production. 2015;91:170-179. https://doi.org/10.1016/j.jclepro.2014.12.043.
9 Duarte AK, Figueiredo AO Jr. Introdução a Refratários. In: Associação Brasileira de Metalurgia, Materiais e Mineração. Refratários para siderurgia. Curso da ABM. São Paulo: ABM; 2023.
10 Duarte AK. Fundamentos em refratários. In: Seminários ALAFAR 2015; 2015; Santiago do Chile. Santiago do Chile; 2015.
11 Zhu T, Li Y, Sang S, Xie Z. A new approach to fabricate MgO-C refractories with high thermal shock resistance by adding artificial graphite. Journal of the European Ceramic Society. 2018;38(4):2179-2185. https://doi.org/10.1016/j. jeurceramsoc.2017.10.018.
12 Luz AP, Souza TM, Pagliosa C, Brito MAM, Pandolfelli VC. In situ hot elastic modulus evolution of MgO–C refractories containing Al, Si or Al–Mg antioxidants. Ceramics International. 2016;42(8):9836-9843. https://doi. org/10.1016/j.ceramint.2016.03.080.
13 Sarkar R. Refractory technology: fundamentals and applications. Boca Raton: CRC Press; 2016. https://doi. org/10.1201/9781315368054.
14 Akkurt S, Leigh HD. Corrosion of MgO-C ladle refractories. Bulletin of the American Ceramic Society. 2003;82(5):9201-9206.
15 Borges RAA, Lenz e Silva GFB. A statistical and post-mortem study of wear and performance of MgO-C resin bonded refractories used on the slag line ladle of a basic oxygen steelmaking plant. Engineering Failure Analysis. 2017;78:161-168. https://doi.org/10.1016/j.engfailanal.2017.03.020.
16 Zhang S, Lee WE. Use of phase diagrams in studies of refractories corrosion. International Materials Reviews. 2000;45(2):41-58. https://doi.org/10.1179/095066000101528304.
17 Bragança SR. Corrosão de refratários utilizados na siderurgia. Parte II: propriedades físicas dos refratários e fatores operacionais. Cerâmica. 2012;58(348):459-464. https://doi.org/10.1590/S0366-69132012000400007.
18 Zhang P, Seetharaman S. Dissolution of MgO in CaO–FeO–CaF2 –SiO2 slags under static conditions. Journal of the American Ceramic Society. 1994;77(4):970-976. https://doi.org/10.1111/j.1151-2916.1994.tb07254.x.
Submitted date:
10/28/2025
Accepted date:
02/02/2026
