Regression modeling to predict ultrafine particles emission in a mineral plant combining meteorological and process variables
Elisangela Krauss, Monica Lopes Aguiar
Abstract
Ultrafine particles are object of main health concern, but its concentration is challenging to be continuous monitored in mineral and metallurgical industrial processes. This paper shows the development of an empirical regression model correlating the ultrafine particles concentration measured by two continuous analyzers, electrodynamic (EDA) and optical scatter (OSA) with meteorological and process parameters. The analyzers were installed at stack of an industrial mineral fertilizer plant over 4 seasons. The results showed that EDA have poor correlation with process or meteorological parameters (r-squared less than 10%) what can be caused by particles not being charged evenly on the stream as its better accuracy for particles over 10µm, as previous studies had suggested. The OSA ultrafine particles concentration model showed r-squared of 45% correlation with meteorological parameters and raw material feed. The model presented and standard error of 0.21 mg/Nm3 which is considered adequate for industry compliance purposes. OSA shows promising application if meteorological parameters are included, as already in practice for ultrafine particles monitoring outdoors.
Keywords
Referências
1 IFASTAT. Nitrogen products. 2019 Jan 29 [cited 2019 Dec 6]. Available at: https://www.ifastat.org/supply/Nitrogen%20Products/AN%20and%20CAN
2 Dhananjayan V, Ravichandran B, Sen S, Panjakumar K. Source, effect, and risk assessment of nanoparticles with special reference to occupational exposure. In: Grumezescu AM, editor. Nanoarchitectonics in biomedicine. San Diego: Elsevier; 2019 [cited 2019 Dec 6]. Available at: https://sciencedirect.com/science/article/pii/b9780128162002000049
3 World Health Organization. Air quality guidelines: global update 2005. Geneva: WHO; 2006 [cited 2020 Feb 15]. Available at: https://www.who.int/phe/health_topics/outdoorair/outdoorair_aqg/en/
4 Séquier F, Faivre V, Daste G, Renouard M, Lesieur S. Critical parameters involved in producing microspheres by prilling of molten lipids: from theoretical prediction of particle size to practice. European Journal of Pharmaceutics and Biopharmaceutics. 2014;87(3):530-540.
5 Hussain I. The operating experience of a nithophosphate plant. In: Proceedings of the 1st International Symposium on Innovation and Technology in the Phosphate Industry; 2012; Morocco. Morocco: OCP Group; 2012.
6 Couper JR, Penney WR, Fair JR, Walas SM. Chemical process equipment. 3rd ed. Amsterdam: Elsevier; 2012. Dryers and cooling towers; p. 223-275.
7 Partridge L, Wong D, Simmons M, Părău EI, Decent S. Experimental and theoretical description of the break-up of curved liquid jets in the prilling process. Chemical Engineering Research & Design. 2005;83(11):1267-1275.
8 Wong D, Simmons M, Decent S, Parau E, King A. Break-up dynamics and drop size distributions created from spiralling liquid jets. International Journal of Multiphase Flow. 2004;30(5):499-520.
9 Shirley AR, Forsythe PA, Giles WM, Phillips JAF. Process for the reducing emissions during prilling of material such as ammonium nitrate. United States patent US 5514307. 1996.
10 Wilson WE, Chow JC, Claiborn C, Fusheng W, Engelbrecht JP, Watson JG. Monitoring of particulate matter outdoors. Chemosphere. 2002;49(9):1009-1043.
11 Thakur P. Advanced mine ventilation: respirable coal dust, combustible gas and mine fire control. Duxford: Elsevier; 2019. p. 189-210.
12 Galvão ES, Santos JM, Lima AT, Reis NC Jr, Orlando MTD, Stuetz RM. Trends in analytical techniques applied to particulate matter characterization: a critical review of fundaments and applications. Chemosphere. 2018;199:546-568.
13 Sullivan RC, Gorkowski K, Jahn L. Characterization of individual aerosol particles. In: Faust J, House J, editors. Physical chemistry of gase liquid interfaces. Amsterdam: Elsevier; 2018.
14 Elsevier BV. Science Direct. 2020 [cited 2020 Apr 5]. Available at: https://www.sciencedirect.com/
15 Padoan E, Ajmone-Marsan F, Querol X, Amato F. An empirical model to predict road dust emissions based on pavement and traffic characteristics. Environmental Pollution. 2018;237:713-720.
16 Moser P, Wiechers GK, Stahl T, Stoffregen G, Vorberg G, Lozano GA. Solid particles as nuclei for aerosol formation and cause of emissions: results from the post-combustion capture pilot plant at Niederaussem. Energy Procedia. 2017;114:1000-1016.
17 Dekati Ltd. [internet]. 2020 [cited 2020 Jan 17]. Available at: https://www.dekati.com/products/elpi/
18 PCME Ltd. [internet]. 2018 [cited 2018 Oct 12]. Available at: https://www.pcme.com
19 Soysal U, Géhin E, Algré E, Berthelot B, Da G, Robine E. Aerosol mass concentration measurements: Recent advancements. Journal of Aerosol Science. 2017;114:42-54.
20 Fahlman BD. Materials chemistry. Dordrecht: Springer; 2007. p. 282-283.
21 Yin Z, Ye X, Jiang S, Tao Y, Shi Y, Yang X, et al. Size-resolved effective density of urban aerosols in Shanghai. Atmospheric Environment. 2015;100:133-140.
22 Wu Y, Bao C, Zhou Y. An innovated tower-fluidized bed prilling process. Chinese Journal of Chemical Engineering. 2007;15(3):424-428.
23 Lee KY, Ling TY, Chan CK. Understanding hygroscopic growth and phase transformation of aerosols using single particle Raman spectroscopy in an electrodynamic balance. Faraday Discussions. 2008;137:245-263.
24 Fertilizers Europe. Production of NPK fertilizers by the nitrophosphate route. Brussels; 2000.
25 Xu Y. Evaluation of mineral dust aerosol optical depth and related components from the CHIMERE-DUST model using satellite remote sensing and ground-based observations. Atmospheric Environment. 2018;191:395-413.
26 Sieniutycz S, Szwast Z. Optimizing thermal, chemical, and environmental systems. Amsterdam: Elsevier; 2018. Neural networks for emission prediction of dust pollutants; p. 87-108 [cited 2019 June 4]. Available at: https://sciencedirect.com/science/article/pii/b9780128135822000033
27 Denby B, Ketzel M, Ellermann T, Stojiljkovic A, Kupiainen K, Niemi JV, et al. Road salt emissions: a comparison of measurements and modelling using the NORTRIP road dust emission model. Atmospheric Environment. 2016;141:508-522.
28 Gong Z, Pan Y-L, Videen G, Wang C. Optical trapping and manipulation of single particles in air: principles, technical details, and applications. Journal of Quantitative Spectroscopy & Radiative Transfer. 2018;214:94-119.
29 Mitchem L, Reid JP. Optical manipulation and characterisation of aerosol particles using a single-beam gradient force optical trap. Chemical Society Reviews. 2008;37(4):756-769.
Submetido em:
03/08/2020
Aceito em:
10/02/2021